CAJ | 학술논문

利用电喷雾电离质谱(ESI-MS)研究了3种金属卟啉化合物(MTPP=MnTPP，FeTPP和CoTPP)，探讨了在这些化合物中苯取代基与卟啉环间的键合能力以及金属卟啉与咪唑的配位情况。研究结果表明，金属卟啉的外围取代基苯基与卟啉环的键合能力按Mn、Fe和Co的次序变弱。金属卟啉与咪唑形成的络合物的离子丰度随配体浓度的增加而增强；在相同的配体浓度下，络合物的离子丰度按Mn、Fe和Co顺序依次增加，其中，CoTPP络合物的稳定性最强。
이용전분무전리질보(ESI-MS)연구료3충금속계람화합물(MTPP=MnTPP，FeTPP화CoTPP)，탐토료재저사화합물중분취대기여계람배간적건합능력이급금속계람여미서적배위정황。연구결과표명，금속계람적외위취대기분기여계람배적건합능력안Mn、Fe화Co적차서변약。금속계람여미서형성적락합물적리자봉도수배체농도적증가이증강；재상동적배체농도하，락합물적리자봉도안Mn、Fe화Co순서의차증가，기중，CoTPP락합물적은정성최강。
Three compounds of metalloporphyrins were studied using electrospray ionization mass spectrometry.The bonding power between substitutional phenyl and porphyrin cycle and the coordinate conditions of metalloporphyrins with imidazole were disscused. The experimental result indicated that the bonding power between substitutional phenyl and porphyrin cycle in metalloporphyrins became weak from Mn,Fe to Co.The complexes abundances formed by metallophorphyrin with imidazole were stronger with the increase of the ligand concentration.At the same ligand concentration,the abundance of the complexes was intensified gradually and the stability of the ligands was become stronger from Mn,Fe to Co.